Ordained in 1974, Marinucci has served at parishes including St. Bernard (1974 to 1978), St. Bartholomew (1978-83), St. Clement, (2000-01), and St. Agatha/St. James (2001-10), all in Philadelphia, as well as Our Lady of Fatima in Bensalem (1983-85), St. John the Evangelist in Morrisville (1985-90), and St. Charles Borromeo Seminary in Wynnewood (1990-2000). He worked at schools including St. Hubert Catholic High School for Girls (1975-79), and Little Flower Catholic High School for Girls (1980-83), both in Philadelphia.